作者：Ram, Natalie; Prince, Anya E. R.; Roberts, Jessica L.; Fox, Dov; Spector-Bagdady, Kayte
作者单位：University System of Maryland; University of Maryland Baltimore; Johns Hopkins University; University of Iowa; Emory University; University of San Diego; University of Michigan System; University of Michigan
作者：Dietz, Maximilian; Protchenko, Andrey V.; Crumpton, Agamemnon E.; Karwasara, Surendar; Roy, Matthew M. D.; Stewart-Moreno, James; Timmel, Christiane; Aldridge, Simon
作者单位：University of Oxford
摘要：In contrast to transition elements, s- and p-block metal compounds that coordinate carbon monoxide (CO) under near-ambient conditions are elusive. Here, we report an isolable, crystalline main-group metal carbonyl complex and its isomerization to a carbene-stabilized metal atom. The stannylene (Boryl)2Sn [where Boryl is B(NDippCH)2] coordinates CO reversibly, affording an isolable adduct below 0 degrees C, which was characterized by x-ray crystallography. This complex rearranges at temperature...
作者：Shen, Lili; Ren, Fei; Wang, Yin-Chu; Li, Zhenhua; Zheng, Mengyuan; Li, Xiaoyi; Fan, Wenzheng; Yang, Yanyan; Sang, Min; Liu, Cheng; Han, Guangye; Qin, Song; Fan, Jianhua; Tian, Lijin; Kuang, Tingyun; Shen, Jian-Ren; Wang, Wenda
作者单位：Chinese Academy of Sciences; Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS; Chinese Academy of Sciences; Yantai Institute of Coastal Zone Research, CAS; Shihezi University; Okayama University
摘要：Photosystem I (PSI) is a pigment-protein complex, which converts light energy into chemical energy in photosynthesis. Among photosynthetic organisms, PSI-LHC (light-harvesting complex) structures exhibit substantial differences in their sizes, reflecting adaptation to different light environments. Here we report the structure of a PSI-fucoxanthin chlorophyll a/c binding protein (FCPI) supercomplex from the coccolithophore Emiliania huxleyi (Eh) at 2.79-angstrom resolution by cryo-electron micr...
