作者：D'Ippoliti, Carlo
作者单位：Sapienza University Rome
作者：Xia, Yuanxing
作者单位：Southeast University - China
作者：Bakhoum, Samuel F.
作者单位：Memorial Sloan Kettering Cancer Center; Memorial Sloan Kettering Cancer Center
作者：Klinger, Madeline
作者单位：University of California System; University of California Berkeley
作者：Bergh, Cathrine
作者单位：Royal Institute of Technology
作者：Hioki, Yuta; Costantini, Matteo; Griffin, Jeremy; Harper, Kaid C.; Merini, Melania Prado; Nissl, Benedikt; Kawamata, Yu; Baran, Phil S.
作者单位：Scripps Research Institute; Mitsubishi International Corporation (MIC); Mitsubishi Chemical Holdings Corporation; Mitsubishi Chemical
摘要：The Kolbe reaction forms carbon-carbon bonds through electrochemical decarboxylative coupling. Despite more than a century of study, the reaction has seen limited applications owing to extremely poor chemoselectivity and reliance on precious metal electrodes. In this work, we present a simple solution to this long-standing challenge: Switching the potential waveform from classical direct current to rapid alternating polarity renders various functional groups compatible and enables the reaction...
作者：Thorp, H. Holden; Vinson, Valda; Yeston, Jake
