作者:Li, Fu; Liu, Shao-Feng; Liu, Wangyu; Hou, Zheng-Wei; Jiang, Jiaxi; Fu, Zhong; Wang, Song; Si, Yilong; Lu, Shaoyong; Zhou, Hongwei; Liu, Dan; Tian, Xiaoli; Qiu, Hengwei; Yang, Yuchen; Li, Zhengcao; Li, Xiaoyan; Lin, Linhan; Sun, Hong-Bo; Zhang, Hao; Li, Jinghong
作者单位:Tsinghua University; Chinese Academy of Sciences; Shanghai Institute of Microsystem & Information Technology, CAS; Tsinghua University; Tsinghua University; Tsinghua University; Tsinghua University; Chinese Academy of Sciences; University of Science & Technology of China, CAS
摘要:3D printing of inorganic materials with nanoscale resolution offers a different materials processing pathway to explore devices with emergent functionalities. However, existing technologies typically involve photocurable resins that reduce material purity and degrade properties. We develop a general strategy for laser direct printing of inorganic nanomaterials, as exemplified by more than 10 semiconductors, metal oxides, metals, and their mixtures. Colloidal nanocrystals are used as building b...
作者:Wang, Xiaoping; Zhou, Yunqiao
作者单位:Chinese Academy of Sciences; Institute of Tibetan Plateau Research, CAS; Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS
作者:Pearson, Tyler J.; Shimazumi, Ryoma; Driscoll, Julia L.; Dherange, Balu D.; Park, Dong-Il; Levin, Mark D.
作者单位:University of Chicago
摘要:Nitrogen scanning in aryl fragments is a valuable aspect of the drug discovery process, but current strategies require time-intensive, parallel, bottom-up synthesis of each pyridyl isomer because of a lack of direct carbon-to-nitrogen (C-to-N) replacement reactions. We report a site-directable aryl C-to-N replacement reaction allowing unified access to various pyridine isomers through a nitreneinternalization process. In a two-step, one-pot procedure, aryl azides are first photochemically conv...