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作者:Holycross, M.; Cottrell, E.
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作者:Brainard, Jeffrey
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作者:Caplan, Arthur
作者单位:New York University
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作者:Sweasy, Joann B.; Hanawalt, Philip C.
作者单位:University of Arizona; Stanford University
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作者:[Anonymous]
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作者:Charles, Dan
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作者:Clery, Daniel; Voosen, Paul
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作者:Scanlon, Seth Thomas; Smith, Keith T.; Yeston, Jake; Lavine, Marc S.; Lopez, Bianca; Malo, Courtney; VanHook, Annalisa M.; Uzogara, Ekeoma; Hurtley, Stella M.; Kelly, Priscilla N.; Grocholski, Brent; Maroso, Mattia; Isles, Hannah M.
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作者:Wailoo, Keith A.; Dzau, Victor J.; Yamamoto, Keith R.
作者单位:Princeton University; National Academies of Sciences, Engineering & Medicine; University of California System; University of California San Francisco; University of California System; University of California San Francisco
摘要:The social benefit of technologies is frequently unevenly realized across the United States. Rural communities, individuals with disabilities, and historically marginalized groups face out-of-reach costs or lack access to products that meet their needs. Blame is typically placed on complicated regulatory processes or complex delivery systems, but this response neglects the problem that equity is not baked into the nation's innovation process at any stage. The United States needs to rethink its...
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作者:Luo, Yongrui; Li, Yuli; Wu, Jian; Xue, Xiao-Song; Hartwig, John F.; Shen, Qilong
作者单位:Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS; Shanghai Institute of Organic Chemistry, CAS; University of California System; University of California Berkeley
摘要:The step that cleaves the carbon-halogen bond in copper-catalyzed cross-coupling reactions remains ill defined because of the multiple redox manifolds available to copper and the instability of the highvalent copper product formed. We report the oxidative addition of a-haloacetonitrile to ionic and neutral copper(I) complexes to form previously elusive but here fully characterized copper(III) complexes. The stability of these complexes stems from the strong Cu-CF3 bond and the high barrier for...