作者:Zhang, Zhen; Quinn, Ethan C.; Kenny, Jacob K.; Grigoropoulos, Alexandra; DesVeaux, Jason S.; Chen, Tiffany; Zhou, Li; Xu, Ting; Beckham, Gregg T.; Chen, Eugene Y. -X.
作者单位:Colorado State University System; Colorado State University Fort Collins; United States Department of Energy (DOE); National Renewable Energy Laboratory - USA; University of California System; University of California Berkeley; University of California System; University of California Berkeley; United States Department of Energy (DOE); Lawrence Berkeley National Laboratory; South China University of Technology
摘要:Commercial adhesives are petroleum-based thermoset networks or nonbiodegradable thermoplastic hot melts, making them ideal targets for replacement by biodegradable alternatives. Poly(3-hydroxybutyrate) (P3HB) is a biorenewable and biodegradable alternative to conventional plastics, but microbial P3HB, which has a stereoperfect stereomicrostructure, exhibits no adhesion. In this study, by elucidating the fundamental relationship between chemocatalytically engineered P3HB stereomicrostructures a...