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作者:Brainard, Jeffrey; Servick, Kelly
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作者:Croft, Catherine
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作者:Mervis, Jeffrey
摘要:Michael Kratsios and Lynne Parker, veterans of Trump's first term, come with technology backgrounds
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作者:Voosen, Paul
摘要:Narrowing storm bands may be a surprising and dangerous new feedback of climate change
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作者:Greenbaum, Dov; Gerstein, Mark
作者单位:Reichman University; Reichman University; Reichman University; Yale University; Yale University; Yale University
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作者:O'Grady, Cathleen
摘要:New focus on challenge-led funding may see decades-old institutes close, scientists warn
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作者:Brainard, Jeffrey
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作者:Piper, Samantha L.; Melag, Leena; Kar, Mega; Sourjah, Azra; Xiao, Xiong; May, Eric F.; Aguey-Zinsou, Kondo-Francois; MacFarlane, Douglas R.; Pringle, Jennifer M.
作者单位:Deakin University; University of Western Australia; University of Sydney; Monash University; Commonwealth Scientific & Industrial Research Organisation (CSIRO); CSIRO Mineral Resources
摘要:Barocaloric (BC) materials offer the potential for highly energy-efficient refrigeration by generating heat absorption through the effect of pressure on a solid-solid phase transition. However, very few of the known materials have the required phase transition in the temperature regions necessary for domestic refrigeration or air conditioning. We introduce organic ionic plastic crystals (OIPCs) as a new family of BC materials. OIPCs display subambient transition temperatures, so-called colossa...
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作者:Brainard, Jeffrey; Servick, Kelly
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作者:Ghosh, Bidhan; Kafle, Prakash; Mukherjee, Rishav; Welles, Randall; Herndon, Deacon; Nicholas, Kenneth M.; Shao, Yihan; Sharma, Indrajeet
作者单位:University of Oklahoma System; University of Oklahoma - Norman
摘要:Given the prevalence of nitrogen-containing heterocycles in commercial drugs, selectively incorporating a single nitrogen atom is a promising scaffold hopping approach to enhance chemical diversity in drug discovery libraries. We harness the distinct reactivity of sulfenylnitrenes, which insert a single nitrogen atom to transform readily available pyrroles, indoles, and imidazoles into synthetically challenging pyrimidines, quinazolines, and triazines, respectively. Our additive-free method fo...