Quantum coherent Chladni-like resonance: Programming ions as matter waves for subpicosecond conduction

• 成果类型: Article
• 署名作者: Sezen, Yaren; Ciftci, Niyazi Okan; Sarsil, Mehmet Ali; Czelej, Kamil; Ergen, Onur
• 署名单位: Istanbul Technical University; Istanbul Technical University; Warsaw University of Technology; Consiglio Nazionale delle Ricerche (CNR); Istituto di Nanotecnologia (NANOTEC-CNR)
• 刊物名称: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
• ISSN/ISSBN: 0027-8424; 1091-6490
• DOI: 10.1073/pnas.2604081123
• 发表日期: 2026-06-09
• 页码: e2604081123
• 关键词: programmable matter; Chladni-like resonance; coherent ions

摘要

Achieving coherent control of ionic transport in solids, analogous to electron waveguides, remains a fundamental challenge, as ionic motion is typically limited by slow, stochastic hopping. Here, we demonstrate that a two-dimensional electrochemical cell (borophene/h-BN/graphene) possesses a collective ionic eigenmode, which, when resonantly excited by a critical-frequency electrical pulse (10 kHz), transforms ionic conduction from diffusive drift into a coherent, ballistic wave. Time-resolved pump-probe spectroscopy directly reveals this transition through the emergence of a strong 28 THz oscillation, a spectroscopic fingerprint of subpicosecond, wavelike motion. The entire intercalated ion ensemble moves in phase, traversing the 80 nm channel as a coherent wave packet in under 300 fs, corresponding to >1,000-fold speed enhancement over classical diffusion. Leveraging this resonant control principle, we realize an electrochemical device that can be charged in picoseconds with a laser pulse. This work demonstrates that quantum-level, Chladni-like resonance is achievable for ionic matter, establishing a universal pathway to programmable, ultrafast coherent ionic conduction. By transforming ions from disordered particles into controllable matter-waves, we unlock the field of coherent ionics for picosecond-scale energy storage and neuromorphic computing.