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作者:Khelifa, Rassim
作者单位:Concordia University - Canada
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作者:Kupferschmidt, Kai
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作者:Song, Yongyong; Xue, Dongqian; Ma, Beibei; Xia, Siyou; Ye, Hao
作者单位:Shaanxi Normal University; Chinese Academy of Sciences; Institute of Geographic Sciences & Natural Resources Research, CAS; Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS
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作者:Fu, Xianbiao; Pedersen, Jakob B.; Zhou, Yuanyuan; Saccoccio, Mattia; Li, Shaofeng; Salinas, Rokas; Li, Katja; Andersen, Suzanne Z.; Xu, Aoni; Deissler, Niklas H.; Mygind, Jon Bjarke Valbaek; Wei, Chao; Kibsgaard, Jakob; Vesborg, Peter C. K.; Norskov, Jens K.; Chorkendorff, Ib
作者单位:Technical University of Denmark
摘要:Ammonia is a critical component in fertilizers, pharmaceuticals, and fine chemicals and is an ideal, carbon-free fuel. Recently, lithium-mediated nitrogen reduction has proven to be a promising route for electrochemical ammonia synthesis at ambient conditions. In this work, we report a continuous-flow electrolyzer equipped with 25-square centimeter-effective area gas diffusion electrodes wherein nitrogen reduction is coupled with hydrogen oxidation. We show that the classical catalyst platinum...
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作者:Tan, Joshua
作者单位:National Institutes of Health (NIH) - USA; Division of Intramural Research (DIR); NIH National Institute of Allergy & Infectious Diseases (NIAID)
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作者:Feller, Ate; Porter, Megan
作者单位:Union College
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作者:Ruan, Lin-Xin; Sun, Bo; Liu, Jia-Ming; Shi, Shi-Liang
作者单位:Chinese Academy of Sciences; University of Chinese Academy of Sciences, CAS; Shanghai Institute of Organic Chemistry, CAS
摘要:Despite the importance of enantioenriched alcohols in medicinal chemistry, total synthesis, and materials science, the efficient and selective construction of enantioenriched tertiary alcohols bearing two contiguous stereocenters has remained a substantial challenge. We report a platform for their preparation through the enantioconvergent, nickel-catalyzed addition of organoboronates to racemic, nonactivated ketones. We prepared several important classes of a,b-chiral tertiary alcohols in a si...
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作者:Ebrahim, Shimaa A. M.; Dweck, Hany K. M.; Weiss, Brian L.; Carlson, John R.
作者单位:Yale University; Yale University
摘要:Tsetse flies transmit trypanosomes-parasites that cause devastating diseases in humans and livestock-across much of sub-Saharan Africa. Chemical communication through volatile pheromones is common among insects; however, it remains unknown if and how such chemical communication occurs in tsetse flies. We identified methyl palmitoleate (MPO), methyl oleate, and methyl palmitate as compounds that are produced by the tsetse fly Glossina morsitans and elicit strong behavioral responses. MPO evoked...
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作者:Clery, Daniel
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作者:Hess, Evan M.; Gould, Todd D.
作者单位:University System of Maryland; University of Maryland Baltimore; University System of Maryland; University of Maryland Baltimore; University System of Maryland; University of Maryland Baltimore