Sustainable, low- cost, high- contrast electrochromic displays via host-guest interactions

• 成果类型: Article
• 署名作者: Wang, Yuyang; Lei, Chuxin; Guan, Weixin; Shi, Wen; Shen, Ruipeng; Zhang, Sean Xiao- An; Yu, Guihua
• 署名单位: University of Texas System; University of Texas Austin; University of Texas System; University of Texas Austin; Jilin University
• 刊物名称: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
• ISSN/ISSBN: 0027-14440
• DOI: 10.1073/pnas.2401060121
• 发表日期: 2024-04-30
• 关键词: reversible metal electrodeposition; amylose; starch; windows

摘要

Electrochromic (EC) displays with electronically regulating the transmittance of solar radiation offer the opportunity to increase the energy efficiency of the building and electronic products and improve the comfort and lifestyle of people. Despite the unique merit and vast application potential of EC technologies, long - awaited EC windows and related visual content displays have not been fully commercialized due to unsatisfactory production cost, durability, color, and complex fabrication processes. Here we develop a unique EC strategy and system based on the natural host and guest interactions to address the above issues. A completely reusable and sustainable EC device has been fabricated with potential advantages of extremely low cost, ideal user - /environment friendly property, and excellent optical modulation, which is benefited from the extracted biomass EC materials and reusable transparent electrodes involved in the system. The as - prepared EC window and nonemissive transparent display also show comprehensively excellent properties: high transmittance change (>85%), broad spectra modulation covering Ultraviolet (UV), Visible (Vis) to Infrared (IR) ranges, high durability (no attenuation under UV radiation for more than 1.5 mo), low open voltage (0.9 V), excellent reusability (>1,200 cycles) of the device's key components and reversibility (>4,000 cycles) with a large transmittance change, and pleasant multicolor. It is anticipated that unconventional exploration and design principles of dynamic host-guest interactions can provide unique insight into different energysaving and sustainable optoelectronic applications.