Hydrogenation of CO2 for sustainable fuel and chemical production

• 成果类型: Review
• 署名作者: Ye, Jingyun; Dimitratos, Nikolaos; Rossi, Liane M.; Thonemann, Nils; Beale, Andrew M.; Wojcieszak, Robert
• 署名单位: Duquesne University; University of Bologna; Universidade de Sao Paulo; Leiden University - Excl LUMC; Leiden University; University of London; University College London; UK Research & Innovation (UKRI); Science & Technology Facilities Council (STFC); STFC Rutherford Appleton Laboratory; Centre National de la Recherche Scientifique (CNRS); Universite de Lorraine; Universite de Lille; Centre National de la Recherche Scientifique (CNRS); CNRS - Institute of Chemistry (INC); Universite d'Artois; Centrale Lille
• 刊物名称: SCIENCE
• ISSN/ISSBN: 0036-10537
• DOI: 10.1126/science.adn9388
• 发表日期: 2025-02-28
• 关键词: life-cycle assessment; methanol synthesis; carbon-dioxide; active-sites; cu catalysts; promotion; oxide; technologies; selectivity; activation

摘要

Catalytic carbon dioxide (CO2) hydrogenation is a potential route for producing sustainable fuels and chemicals, but existing catalysts need improvement. In particular, identifying active sites and understanding the interaction between components and the dynamic behavior of the participant species remain unclear. This fundamental knowledge is essential for the design of more efficient and stable catalysts. Because the nature of the active site (metal, oxide, carbide) is the main factor that determines the catalytic activity of the catalysts, this Review focuses on various types of heterogeneous catalysts that have been recently reported in the literature as efficient for CO2 conversion to C1 [carbon monoxide (CO), methanol (CH3OH), methane (CH4)], and higher hydrocarbons. We focus on establishing key connections between active-site structures and selectivity, regardless of catalyst composition.