Encapsulated Co-Ni alloy boosts high-temperature CO2 electroreduction

• 成果类型: Article
• 署名作者: Ma, Wenchao; Morales-Vidal, Jordi; Tian, Jiaming; Liu, Meng-Ting; Jin, Seongmin; Ren, Wenhao; Taubmann, Julian; Chatzichristodoulou, Christodoulos; Luterbacher, Jeremy; Chen, Hao Ming; Lopez, Nuria; Hu, Xile
• 署名单位: Swiss Federal Institutes of Technology Domain; Ecole Polytechnique Federale de Lausanne; Barcelona Institute of Science & Technology; National Taiwan University; National Taiwan University; Swiss Federal Institutes of Technology Domain; Ecole Polytechnique Federale de Lausanne; Technical University of Denmark
• 刊物名称: Nature
• ISSN/ISSBN: 0028-1254
• DOI: 10.1038/s41586-025-08978-0
• 发表日期: 2025-05-29
• 关键词: total-energy calculations; high-performance; oxide; electrolysis; cathode; points; cells

摘要

Electrochemical CO2 reduction into chemicals and fuels holds great promise for renewable energy storage and carbon recycling1, 2-3. Although high-temperature CO2 electroreduction in solid oxide electrolysis cells is industrially relevant, current catalysts have modest energy efficiency and a limited lifetime at high current densities, generally below 70% and 200 h, respectively, at 1 A cm-2 and temperatures of 800 degrees C or higher4, 5, 6, 7-8. Here we develop an encapsulated Co-Ni alloy catalyst using Sm2O3-doped CeO2 that exhibits an energy efficiency of 90% and a lifetime of more than 2,000 h at 1 A cm-2 for high-temperature CO2-to-CO conversion at 800 degrees C. Its selectivity towards CO is about 100%, and its single-pass yield reaches 90%. We show that the efficacy of our catalyst arises from its unique encapsulated structure and optimized alloy composition, which simultaneously enable enhanced CO2 adsorption, moderate CO adsorption and suppressed metal agglomeration. This work provides an efficient strategy for the design of catalysts for high-temperature reactions that overcomes the typical trade-off between activity and stability and has potential industrial applications.